Metal-Ion Interactions with Sugars. The Crystal Structure of CaCl2-Fructose Complex
نویسندگان
چکیده
منابع مشابه
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.
Critical biological electron-transfer processes involving high-valent oxometal chemistry occur widely, for example in haem proteins [oxoiron(IV); Fe(IV)(O)] and in photosystem II. Photosystem II involves Ca(2+) as well as high-valent oxomanganese cluster species. However, there is no example of an interaction between metal ions and oxoiron(IV) complexes. Here, we report new findings concerning ...
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The title compound, C6H12O6, was crystallized from an aqueous solution of equimolar mixture of d- and l-fructose (1,3,4,5,6-penta-hydroxy-hexan-2-one, arabino-hexulose or levu-lose), and it was confirmed that d-fructose (or l-fructose) formed β-pyran-ose with a (2) C 5 (or (5) C 2) conformation. In the crystal, two O-H⋯O hydrogen bonds between the hy-droxy groups at the C-1 and C-3 positions, a...
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هدف از انجام این تخقیق بررسی رابطه احتمالی بین سطح مهارت زبان خارجی (foreign language proficiency) و ساختار مهارت زبان خارجی بود. تعداد 314 زبان آموز مونث و مذکر که عمدتا دانشجویان رشته های زبان انگلیسی در سطوح کارشناسی و کارشناسی ارشد بودند در این تحقیق شرکت کردند. از لحاظ سطح مهارت زبان خارجی شرکت کنندگان بسیار با هم متفاوت بودند، (75 نفر سطح پیشرفته، 113 نفر سطح متوسط، 126 سطح مقدماتی). کلا ...
15 صفحه اولSugars, fruits and fructose drinks.
Fructose drinks are being promoted among diabetics. We write this piece to clarify certain nutritional issues about these drinks. With regard to human nutrition, sugars in foods can be divided into two groups: sugars in intact fruits and vegetables (intrinsic sugars) and sugars that are added to food and drinks by manufacturers, cooks or consumers (added sugars), e.g. sucrose, fructose. Sucrose...
متن کاملCrystal structure of fructose-1,6-bisphosphatase complexed with fructose 6-phosphate, AMP, and magnesium.
The crystal structure of fructose-1,6-bisphosphatase (EC 3.1.3.11) complexed with fructose 6-phosphate, AMP, and Mg2+ has been solved by the molecular replacement method and refined at 2.5-A resolution to a R factor of 0.215, with root-mean-square deviations of 0.013 A and 3.5 degrees for bond lengths and bond angles, respectively. No solvent molecules have been included in the refinement. This...
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ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2012
ISSN: 0253-2964
DOI: 10.5012/bkcs.2012.33.6.2028